(a) Show that the variational integral W1 for the ground state of H+2 can be written as...

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(a) Show that the variational integral W1 for the ground state of H+2 can be written as W1 = k2F(t) + kG(t), where t K kR and where F and G are certain functions of t.
(b) Show that the minimization condition ˆ‚W1/ˆ‚k = 0 leads to

Using this equation, we can find k for a given value of t. We then use R = t/k to find the value of R corresponding to our value of k.

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Quantum Chemistry

ISBN: 978-0321803450

7th edition

Authors: Ira N. Levine

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Question Posted: May 26, 2016 06:32 AM

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(a) Show that the variational integral W1 for the ground state of H+2 can be written as...

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a Let t kR Then Eq 1363 becomes The R 1 terms in the numerator are not proportio...View the full answer

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