At room temperature, 1,2-dibromoethane exists as an equilibrium mixture in which 89% of the molecules are in

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At room temperature, 1,2-dibromoethane exists as an equilibrium mixture in which 89% of the molecules are in an anti conformation and 11% are gauche. The comparable ratio for butane under the same circumstances is 72% anti and 28% gauche. Suggest an explanation for the difference, bearing in mind that Br is sterically smaller than CH3.
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Organic Chemistry structure and function

ISBN: 978-1429204941

6th edition

Authors: K. Peter C. Vollhardt, Neil E. Schore

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