Discuss the relationship between wmax and the magnitude and sign of the free energy change for a reaction. Also discuss wmax for real processes.
Answer to relevant QuestionsThe enthalpy of vaporization of chloroform (CHCl3) is 31.4 kJ/ mol at its boiling point (61.7oC). determine ΔSsys, ΔSsurr, and ΔSuniv when 1.00 mole of chloroform is vaporized at 61.7oC and 1.00 atm. Consider the reaction H2(g) + Br2(g) ⇌ 2HBr(g) where ΔHo = 2103.8 kJ. In a particular experiment, 1.00 atm of H2(g) and 1.00 atm of Br2(g) were mixed in a 1.00-L flask at 25oC and allowed to reach equilibrium. Then the ...The standard entropy values (So) for H2O(l) and H2O(g) are 70. JK-1mol-1 and 189 JK-1mol-1, respectively. Calculate the ratio of Vg to Vl for water using Boltzmann’s equation. (See Exercise 22.) One mole of an ideal gas undergoes an isothermal reversible expansion at 25oC. During this process, the system absorbs 855 J of heat from the surroundings. When this gas is compressed to the original state in one step ...Consider 1.00 mole of an ideal gas at 25oC. a. Calculate q, w, ΔE, ΔS, ΔH, and ΔG for the expansion of this gas isothermally and irreversibly from 2.45 × 10-2 atm to 2.45 × 10-3 atm in one step. b. Calculate q, w, ΔE, ...
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