Draw structures analogous to those in Eqs. 18.59a-d for the catalytic intermediates formed in the conversion of
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Draw structures analogous to those in Eqs. 18.59a-d for the catalytic intermediates formed in the conversion of 1, 7-octadiene to cyclohexene and ethylene catalyzed by the G2 catalyst.
Eqs. 18.59a-d
Transcribed Image Text:
NHC NHC NHC RCH CHR C,Ru CHPh a 14e complex + :P(Cy)s RCH CHR P(Cy) a l6e complex cycloaddition cycloreversion NHC NHC NHC NHC CHPh l CHR very minor by-product RCH RCH RCH CHR a metallacycle RCH CHR NHC NHC NHC RCH CHR first metathesis product RCH CHR NHC NHC NHC CI,Ru RCH CH second RCH CHR RCH CHR RCH metathesis product catalyst enters another cycle (Eq. 18.59c)
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