Show that the four functions of (13.89) have the indicated eigen values with respect to a Ïv(xz)

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Show that the four functions of (13.89) have the indicated eigen values with respect to a Ïƒv(xz) reflection of electronic coordinates. Start by showing that this reflection converts Ï• to -Ï• and leaves ra and rb unchanged

'*: 7+1(1)71(2) + 7+1(2)71(1) + 7-(1)71(2) + 7-1(2)71(1) IE: T+1(1)7(2) + 7+1(2)T1(1) - T(1)T',1(2) – T(2)1(1) : 71(1)'1(2) - T+1(2)T'1(1) + T 1(1)'1(2) – T-1(2)

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Quantum Chemistry

ISBN: 978-0321803450

7th edition

Authors: Ira N. Levine

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Question Posted: May 26, 2016 06:32 AM

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Show that the four functions of (13.89) have the indicated eigen values with respect to a Ïv(xz)

Question:

'*: 7+1(1)71(2) + 7+1(2)71(1) + 7-(1)71(2) + 7-1(2)71(1) IE: T+1(1)7(2) + 7+1(2)T1(1) - T(1)T',1(2) – T(2)1(1) : 71(1)'1(2) - T+1(2)T'1(1) + T 1(1)'1(2) – T-1(2)"'41(1) : T1(1)71(2) - 741(2)7(1) – T (1)';1(2) + 71(2)"';1(1)

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Quantum Chemistry

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