Derive expressions for (left(frac{partial c_{v}}{partial v} ight)_{T}) for substances obeying the following laws: (a) (p=frac{Re T}{v-b} mathrm{e}^{-frac{a}{Re
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Derive expressions for \(\left(\frac{\partial c_{v}}{\partial v}\right)_{T}\) for substances obeying the following laws:
(a) \(p=\frac{\Re T}{v-b} \mathrm{e}^{-\frac{a}{\Re T v}}\)
(b) \(p=\frac{\Re T}{v-b}-\frac{a}{T v^{2}}\)
(c) \(p=\frac{\Re T}{v-b}-\frac{a}{v(v-b)}+\frac{c}{v^{3}}\).
Discuss the physical implication of the results.
\(\left[\frac{p a^{2}}{\Re^{2} v^{2} T^{3}} ;-\frac{2 a}{v^{2} T^{2}} ; 0\right]\)
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Related Book For
Advanced Thermodynamics For Engineers
ISBN: 9780080999838
2nd Edition
Authors: D. E. Winterbone, Ali Turan
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