For a van der Waals gas that obeys the state equation [p=frac{R T}{v-mathrm{b}}-frac{mathrm{a}}{v^{2}}] shows that the coefficient

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For a van der Waals gas that obeys the state equation

\[p=\frac{R T}{v-\mathrm{b}}-\frac{\mathrm{a}}{v^{2}}\]


shows that the coefficient of thermal expansion, \(\beta\), is given by \[\beta=\frac{R v^{2}(v-\mathrm{b})}{R T v^{3}-2 \mathrm{a}(v-\mathrm{b})^{2}}\]
and the isothermal compressibility, \(k\), is given by \[k=\frac{v^{2}(v-\mathrm{b})^{2}}{R T v^{3}-2 \mathrm{a}(v-\mathrm{b})^{2}}\]
Also evaluate \(T\left(\frac{\partial p}{\partial v}\right)_{T}\left(\frac{\partial v}{\partial T}\right)_{p}^{2}\) for the van der Waals gas. From this find \(c_{p}-c_{v}\) for an ideal gas, stating any assumptions made in arriving at the solution.

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Related Book For  answer-question

Advanced Thermodynamics For Engineers

ISBN: 9780080999838

2nd Edition

Authors: D. E. Winterbone, Ali Turan

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