A rocket fuel would be useless if its oxidation were not spontaneous. Although rockets operate under conditions

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A rocket fuel would be useless if its oxidation were not spontaneous. Although rockets operate under conditions that are far from standard, an initial estimation of the potential of a rocket fuel might assess whether its oxidation at the high temperatures reached in a rocket is spontaneous. A chemist exploring potential fuels for use in space considered using vaporized aluminum chloride in a reaction for which the skeletal equation isAICI, (g) + O(g) AlO3 (s) + ClO(g)

Balance this equation. Th en use the following data (which are for 2000 K) to decide whether the fuel is worth further investigation: ΔGf° (AlCl3, g) = –467 kJ · mol–1, ΔGf° (Al2O3, s) = –1034 kJ · mol–1, ΔGf° (ClO, g) = +75 kJ · mol–1.

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Chemical Principles The Quest For Insight

ISBN: 9781464183959

7th Edition

Authors: Peter Atkins, Loretta Jones, Leroy Laverman

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