Buckminsterfullerene is an allotrope of carbon in which the carbon atoms form nearly spherical molecules of 60
Question:
Buckminsterfullerene is an allotrope of carbon in which the carbon atoms form nearly spherical molecules of 60 atoms each. In the pure compound, the spheres pack in a cubic close-packed array.
(a) The length of a side of the face-centered cubic cell formed by buckminsterfullerene is 142 pm. Use this information to calculate the radius of the buckminsterfullerene molecule treated as a hard sphere.
(b) The compound K3C60 is a superconductor at low temperatures. In this compound the K+ ions lie in holes in the C603– face-centered cubic lattice. Considering the radius of the K+ ion and assuming that the radius of C603– is the same as for the C60 molecule, predict in what type of holes the K+ ions lie (tetrahedral, octahedral, or both) and indicate what percentage of those holes are filled.
Step by Step Answer:
Chemical Principles The Quest For Insight
ISBN: 9781464183959
7th Edition
Authors: Peter Atkins, Loretta Jones, Leroy Laverman