Buckminsterfullerene is an allotrope of carbon in which the carbon atoms form nearly spherical molecules of 60

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Buckminsterfullerene is an allotrope of carbon in which the carbon atoms form nearly spherical molecules of 60 atoms each. In the pure compound, the spheres pack in a cubic close-packed array.

(a) The length of a side of the face-centered cubic cell formed by buckminsterfullerene is 142 pm. Use this information to calculate the radius of the buckminsterfullerene molecule treated as a hard sphere.

(b) The compound K3C60 is a superconductor at low temperatures. In this compound the Kions lie in holes in the C603– face-centered cubic lattice. Considering the radius of the K+ ion and assuming that the radius of C603– is the same as for the C60 molecule, predict in what type of holes the K+ ions lie (tetrahedral, octahedral, or both) and indicate what percentage of those holes are filled.

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Chemical Principles The Quest For Insight

ISBN: 9781464183959

7th Edition

Authors: Peter Atkins, Loretta Jones, Leroy Laverman

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