Use Appendix 2B to determine whether an acidic sodium dichromate solution can oxidize (a) Bromide ions to
Question:
Use Appendix 2B to determine whether an acidic sodium dichromate solution can oxidize
(a) Bromide ions to bromine and
(b) Silver (I) ions to silver(II) ions under standard conditions.
Transcribed Image Text:
2B STANDARD POTENTIALS AT 25 °C Potentials in Electrochemical Order Reduction half-reaction Strongly oxidizing H4XeO6+ 2 H+2 e → XeO3 + 3 H₂O F22 e 2 F¯ 03 + 2 H+ + 2 e O2 + H₂O S2O8²2 e 2 SO4²- Ag²+ + e → Ag+ CO³+ +e→Co²+ H₂O2 + 2 H+ + 2 e 2 H₂O Aue Au Pb+ + 2 e Pb²+ 2 HCIO + 2 H+2 e→Cl₂ + 2 H₂O Cet + eCe³+ 2 HBrO + 2 H+ + 2 e Br2 + 2 H₂O MnO4 + 8 H+ + 5 e → Mn²+ + 4 H₂O Mn3³+ + e→→ Mn²+ Au³+ + 3 e → Au Cl₂ + 2e 2 Cl Cr₂O7² + 14 H O3 + H₂O + 2e O₂ + 4H+ + 4e + 6 e2 Cr³+ + 7 H₂O → O₂ + 2 OH → 2 H₂O Eº/V +3.0 +2.87 +2.07 +2.05 +1.98 +1.81 +1.78 +1.69 +1.67 +1.63 +1.61 +1.60 +1.51 +1.51 +1.40 +1.36 +1.33 +1.24 +1.23 +1 23 Reduction half-reaction NO3 + H₂O + 2e →NO₂ + 2 OH¯ Ti + e →→ Ti³+ 2 H+ + 2e → H₂ Fe³++3 e Fe O₂ + H₂O + 2 e → HO₂ + OH Pb²+ 2 e Pb In + e →→ In Sn²+ + 2e → Sn Agle → Ag + I Ni²+ + 2e → Ni V³+ + € → V²+ Co²+ +2 e Co In³+ + 3 e → In TI+ + e → Tl PbSO4 + 2 e Pb + SO₂²2² Ti³+ + e Ti²+ In²+ + e → Int Cd²+ + 2 e Cr³+e Fe²+ + 2 e Cd Cr²+ Fe Eº/V +0.01 0.00 0, by definition -0.04 -0.08 -0.13 -0.14 -0.14 -0.15 -0.23 -0.26 -0.28 -0.34 -0.34 -0.36 -0.37 -0.40 -0.40 -0.41 -0.44
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Chemical Principles The Quest For Insight
ISBN: 9781464183959
7th Edition
Authors: Peter Atkins, Loretta Jones, Leroy Laverman
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