You wish to know the enthalpy change for the formation of liquid PCl 3 from the elements.

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You wish to know the enthalpy change for the formation of liquid PCl3 from the elements. P4(s) + 6 Cl(g)  4 PC13(e) A,H = ?

The enthalpy change for the formation of PCl5 from the elements can be determined experimentally, as can the enthalpy change for the reaction of PCl3(ℓ) with more chlorine to give PCl5(s): P4(s) + 10 Cl(g)  4 PC15(s) A,H = -1774.0 kJ/mol-rxn PC13() + Cl(g)   PCL5 (s) A,H = -123.8 kJ/mol-rxn

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Chemistry And Chemical Reactivity

ISBN: 9780357001172

10th Edition

Authors: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel

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