Iron(II) ions react with phenanthroline (C 12 H 8 N 2 ) to form a complex ion

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Iron(II) ions react with phenanthroline (C12H8N2) to form a complex ion with the general formula Fex(C12H8N2)y 2x+. A student uses the method of continuous variation to determine the number of phenanthroline molecules bound to each iron ion (i.e., the values of x and y in the formula). The complex ion is strongly colored, so its concentration can be monitored using a spectrometer. Working with 2.4 × 10-3 M solutions of both Fe3+and C12H8N2, the data shown in the graph below were obtained. What is the correct formula for the complex ion?

Concentration of complex ion 0 10 T 20 30 T 40 50 60 Volume % of Fe+ 70 80 90 100

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Related Book For  answer-question

Chemistry For Engineering Students

ISBN: 9780357026991

4th Edition

Authors: Lawrence S. Brown, Tom Holme

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