Use values from Appendix E at the back of the book to calculate the equilibrium constant, Kp, for the following gaseous reactions:

(a) H₂(g) + Cl₂(g) ⇄ 2 HCl(g)

(b) CH₄(g) + H₂O(g) ⇄ CO(g) + 3 H₂(g)

(c) SO₂(g) + Cl₂(g) ⇄ SO₂Cl₂(g)

(d) 2 HCl(g) + F₂(g) ⇄ 2 HF(g) + Cl₂(g)

Data from appendix E

Transcribed Image Text:

Specles Aluminum Al(s) AICI;(s) Al₂O₂ (s) AIPO4(s) Al₂(SO4),(s) Antimony Sb(s) Sb₂O(s) Sb₂O,(s) SbCl,() SbCl,(s) Argon Ar(g) Arsenic As(s) H₂As(g) As₂Os(s) AsCl₂(e) Barium Ba(s) BaCl₂(s) BaCO,(s) BaF,(s) Ba(NO₂)(s) BaD(s) BaSO4(s) Beryllium Be(s) BeCl₂(s) BeF₂(s) BeO(s) Be(OH)₂(s) BeSO4(s) Species Cas(s) Ca(NO₂)2(s) Ca(OH)₂(s) Ca(OH)₂(aq) Ca,(PO)(s) CaSO4(s) Carbon C(s, graphite) C(s, diamond) C(g) CCL(0) CCL,(g) CHCI,(Ⓒ) CHCI,(g) CH₂Cl₂(g) CH,CI(g) CF.(g) CF₂Cl₂(g) CH,CF,(0) CH₂(g) C₂H₂(g) C₂H₂(g) C₂H₂(g) C₂H₂(g) C₂H₂(g) C₂H₂(g) (n-butane) C₂H₂(e) CH₂OH() C₂H₂OH(Ⓒ) C₂H₂OH(g) HCOOH(aq) HCOOH(0) HCHO(g) CH,CHO(g) CH₂COOH() H₂C₂O4(s) H₂C₂O4(aq) AH, (kJ mol-¹) HCN(g) CH,NH,(g) 0 28.3 -704.2 110.7 -1676 50.92 -1733.8 90.76 -3440.84 239.3 0 -1417.1 -971.9 -440.2 -382.17 184.1 0 0 66.44 -924.87 -305.0 5⁰ (J mol-1 K-¹) 49.03 C,H₁(C)(n-octane) -250.3 45.69 246.0 ΔΗ, (kJ mol ¹) 125.1 301 154.843 0 62.8 -860.1 126 -1216.3 112.1 -1207.1 96.36 -992.07 213.8 -553.5 70.42 -1465 132 35.1 222.78 105.4 216.3 9.54 0 -490.4 82.68 -1026.8 53.35 -609.6 14.14 -907.1 50.2 -1205.20 77.91 Sº (mol 1 K¹) -482.4 56.5 -938.39 193.3 -986.6 76.1 -1002.8 76.15 -4120.8 236.0 -1433 107 0 5.740 1.897 2.38 716.7 158.0 -135.4 216.4 -103 309,7 -134.5 202 -103.1 295.6 -121.46 177.8 -80.83 234.58 -925 261.61 -477 301 -737 280 -74.81 186.2 226.7 200.8 52.26 219.5 -84.86 229.5 20.41 266.9 -103.8 269.9 -126.5 310.03 172.8 361.2 -238.66 126.8 -277.7 161 -235.1 282.6 -425.6 92.0 -424.72 128.95 -108.57 218.77 -166.19 250.3 -484.5 159.8 -828.93 115.6 -825.1 45.61 135.1 23.0 201.78 243.3 AG (kJ mol-¹) 0 -628.9 -1582 -1617.9 -3099.94 0 -1253.0 -829.2 -350.1 -259.4 0 0 68.93 -782.3 -259.4 0 -810.9 -1137.6 -1156.8 -796.59 -525.1 -1353 0 -445.6 -979.4 -580.3 -817.6 -1093.80 AG,⁰ (kJ mol ¹) -477.4 -743.07 -896.8 -867.6 -3884.7 -1320 0 2.900 671.3 -65.27 -60.63 -73.72 -70.37 -67.26 -57.37 -879 -440 -668 -50.75 209.2 68.12 -32.9 62.75 -23.49 -15.71 124.5 16.32 -166.27 -174.9 -168.6 -351 -361.35 -102.53 -128.86 -389.9 -697.2 -673.9 124.7 32.16 Specles Bismuth Bi(s) BiCl(s) Bi₂O,(s) Bi₂S,(s) Boron B(s) BCI,() B₂H,(g) BF,(g) HBO,(s) NaBH4(s) Bromine Br(g) Br₂(e) Br₂(g) BrF, (g) HBr(g) Cadmium Cd(s) CdCl(s) CdO(s) CdS(s) Calcium Ca(s) Ca(g) Ca²+ (aq) CaBr₂(s) CaC₂(s) CaCO₂ (s) CaCl₂(s) CaF₂(s) CaH₂(s) CaO(s) Specles CO(NH,),(s) CH₂CN() C₂H,N() CO(g) CO₂(g) CO,(aq) COCI,(g) CS₂(g) (CH₂) SO() C₂H₁₂O(s) (glucose) C₁₂H₂2O₁1(s) (sucrose) Cesium Cs(s) Cs¹ (aq) CsF(aq) Chlorine Cl₂(g) Cl(g) 1 (g) Cl(aq) CIO(g) CIO₂(g) Cl₂O(g) CIF(g) CIF; (g) HCl(g) HCl(aq) Chromium Cr(s) Cr₂O;(s) CryCl,(s) (NH4)₂Cr₂O,(s) Cobalt Co(s) Coo(s) Co₂O₂ (s) CoCl₂(s) COSO (s) AH,Ⓡ (kJ mol-¹) 0 -379.1 -573.88 -143.1 0 -427.2 111.8 0 30.91 -255.6 -36.4 35.6 232.11 -1137.00 254.12 -1094.33 88.83 -183.34 104.68 0 192.6 -542.8 682.8 -62.8 -1207 -795.0 -1215 -189 -635.5 5⁰ (mol-1 K-¹) AH, (kJ mol ¹) -334 56.74 177.0 151.5 200.4 0 51.76 -391.50 115.27 -258.2 - 161.9 5.86 206.3 0 -248 -568.6 174.9 152.23 245.4 292.4 198,59 54.8 64.9 41.6 154.8 -53.1 130 70.3 92.9 114 68.87 42 40 Sº (J mol 1 K¹) 105 54 150 172.9 188 -110.5 197.6 -393.5 213.6 -413.80 117.6 -223.0 289.2 117.4 237.7 -203 188 -1274.5 212.1 -2221.7 360.24 85.23 133 123 0 121.7 -226 -167.29 56.48 101.22 104.60 80 -54.48 -163.2 281.61 -92.31 186.8 -167.4 55.10 223.0 165.1 249.4 266 217.89 0 23.8 -1139,7 81.2 -556.5 123.0 -1807 0 30.04 -237.94 52.97 -891 102.5 -312.5 -888.3 109.16 118.0 AG, (kJ mol-¹) 0 -315.0 -493.7 -140.6 0 -387.4 86.7 -1120.33 -968.92 -119.54 82.4 0 3.14 -229.5 -53.43 0 -343.93 -228.4 -156.5 0 158.9 -553.5 -663.6 -67.8 -1129 -750.2 -1162 -150 -604.2 AG, (kJ mol ¹) -198 99 208.6 -137.2 -394.4 -385.98 -210.5 67.15 -99 -910.56 - 1544.3 0 -282 -558.5 0 105.7 -131.26 123.4 98 -55.94 -123.0 -95.30 -131.2 0 -1058.1 -486.1 0 -214.20 -774 -269.8 -782.3