Show that it follows directly from the equation of state, P = RT/, that the internal energy
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Show that it follows directly from the equation of state, P = RT/α, that the internal energy of an ideal gas is a function of temperature only.
Solution: from (??) and p = RT/α, we have
But, mathematically,
Equating the coefficients of dT and dα in these two expressions gives
Noting that ∂2η/(∂α∂T) = ∂2η/(∂T∂α) we obtain
Thus, (∂T/∂α)T = 0. Because, in general, the internal energy may be considered either a function of temperature and density or temperature and pressure, this proves that for an ideal gas the internal energy is a function only of temperature.
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Related Book For
Essentials Of Atmospheric And Oceanic Dynamics
ISBN: 9781107692794
1st Edition
Authors: Geoffrey K. Vallis
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