Perform a reduction of the data in Table 11-1 for the di-isopropyl ether (1) + 1-propanol (2)
Question:
Perform a reduction of the data in Table 11-1 for the di-isopropyl ether (1) + 1-propanol (2) system at 303.15 K using both the 1-parameter and 2-parameter Margules equations.
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TABLE 11-1 Experimental Pxy data for the di-isopropyl ether (1) + 1-propanol (2) system at 303.15 K. X₂ P (kPa) 3.77 5.05 6.15 7.22 8.29 10.60 12.16 14.07 15.62 16.81 17.91 18.77 0 0.0199 0.0399 0.0601 0.0799 0.1192 0.1694 0.2294 0.2891 0.3495 0.4090 0.4708 0 Y₁ 0.2671 0.4090 0.5061 0.5783 0.6847 0.7346 0.7822 0.8133 0.8343 0.8524 0.8659 P (kPa) 19.51 20.23 20.71 21.35 21.92 22.62 23.20 23.59 23.80 23.99 24.19 24.36 0.5296 0.5902 0.6505 0.7101 0.7685 0.8300 0.8803 0.9179 0.9397 0.9581 0.9804 y₁ 0.8774 0.8890 0.8974 0.9093 0.9209 0.9372 0.9521 0.9637 0.9709 0.9785 0.9885 1 Based on data from 1. Hwang et al., J. Chem. Eng. Data, 52, 2503 (2007).
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Step 1 Obtain the experimental activity coefficients and the experimental excess molar Gibbs free energy We can obtain the experimental activity coefficients and the excess molar Gibbs free energy in ...View the full answer
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Related Book For
Fundamentals Of Chemical Engineering Thermodynamics
ISBN: 9781111580704
1st Edition
Authors: Kevin D. Dahm, Donald P. Visco
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