For the disproportionation of p-toluenesulfonic acid, (where Ar = p-CH 3 C 6 H 4 ), the
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For the disproportionation of p-toluenesulfonic acid,
(where Ar = p-CH3C6H4—), the following data were obtained: t = 0 min, [ArSO2H] = 0.100 M; 15 min, 0.0863 M; 30 min, 0.0752 M; 45 min, 0.0640 M; 60 min, 0.0568 M; 120 min, 0.0387 M; 180 min, 0.0297 M; 300 min, 0.0196 M.
(a) Show that this reaction is second order.
(b) What is the value of the rate constant, k?
(c) At what time would [ArSO2H] = 0.0500 M?
(d) At what time would [ArSO2H] = 0.0250 M?
(e) At what time would [ArSO2H] = 0.0350 M?
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Related Book For
General Chemistry Principles And Modern Applications
ISBN: 9780132931281
11th Edition
Authors: Ralph Petrucci, Jeffry Madura, F. Herring, Carey Bissonnette
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