The following three-step mechanism has been proposed for the reaction of chlorine and chloroform. The numerical values

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The following three-step mechanism has been proposed for the reaction of chlorine and chloroform.

(1) Cl(g) k1 k-1 (2) Cl(g) + CHCl3(g) (3) CC13(g) + Cl(g) 2 Cl(g) k3 k2 HCl(g) + CC13(g) CC14(g)

The numerical values of the rate constants for these steps are k₁ = 4.8 x 103 ; k^-1 = 3.6 x 10³ ; k₂ = 1.3 x 10^-2; k₃ = 2.7 x 10². Derive the rate law and the magnitude of k for the overall reaction.

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General Chemistry Principles And Modern Applications

ISBN: 9780132931281

11th Edition

Authors: Ralph Petrucci, Jeffry Madura, F. Herring, Carey Bissonnette

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Question Posted: Nov 28, 2023 12:22 AM

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The following three-step mechanism has been proposed for the reaction of chlorine and chloroform. The numerical values

Question:

(1) Cl₂(g) k1 k-1 (2) Cl(g) + CHCl3(g) (3) CC13(g) + Cl(g) 2 Cl(g) k3 k2 HCl(g) + CC13(g) CC14(g)

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To derive the rate law for the overall reaction and determine the magnitude of k we need to follow t...View the full answer

General Chemistry Principles And Modern Applications

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