We have seen that complex formation can stabilize oxidation states. An important illustration of this fact is
Question:
We have seen that complex formation can stabilize oxidation states. An important illustration of this fact is the oxidation of water in acidic solutions by Co3+(aq) but not by [Co(en)3]3+. Use the following data.
Show that [Co(en)3]3+ is stable in water but Co3+(aq) is not.
Transcribed Image Text:
[Co(H₂0)6]³+ + e [Co (H₂O)6]2+ + 3 en [Co(H2O)%]3+ + 3en •[Co(H,O)%]2+ Eº = 1.82 V [Co(en)3]2+ + 6H₂0(1) log B3 = 12.18 • [Co(en)3]3+ +6H,O(1) log B3 = 47.30 Calculate E° for the reaction [Co(en)3]³+ + e → [Co(en)3]²+
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Related Book For
General Chemistry Principles And Modern Applications
ISBN: 9780132931281
11th Edition
Authors: Ralph Petrucci, Jeffry Madura, F. Herring, Carey Bissonnette
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