(a) Comment on the relevance of studying complexes such as [Fe(CN) 4 (CO) 2 ] 2 and...
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(a) Comment on the relevance of studying complexes such as [Fe(CN)4(CO)2]2− and [Fe(CO)3(CN)3]− as models for the active sites of [NiFe]- and [FeFe]-hydrogenases.
(b) Describe the structure of the FeMo cofactor in nitrogenase. Until 2002, when a central ligand was located in the FeMo cofactor, it was suggested that N2 binding might take place at 3-coordinate iron sites. Explain why this proposal is no longer plausible.
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a Comment on the relevance of studying complexes such as FeCN4CO22 and FeCO3CN3 as models for the active sites of NiFe and FeFehydrogenases The study of complexes such as FeCN4CO22 and FeCO3CN3 is rel...View the full answer
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