(a) The value of eff for [CoF 6 ] 3 is 5.63 B . Explain...

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(a) The value of μ_eff for [CoF₆]³⁻ is 5.63 μ_B. Explain why this value does not agree with the value for μ calculated from the spin-only formula.

(b) By using a simple MO approach, rationalize why one-electron oxidation of the bridging ligand in [(CN)₅CoOOCo(CN)₅]⁶⁻ leads to a shortening of the O—O bond.

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Inorganic Chemistry

ISBN: 9781292134147

5th Edition

Authors: Catherine Housecroft

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Question Posted: Jul 26, 2023 03:27 AM

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(a) The value of eff for [CoF 6 ] 3 is 5.63 B . Explain...

Question:

[Ni(acac)3], [CoCl3 (NCMe)], cis-[Co(en)₂Cl₂], trans-[Cr(en)₂Cl₂]¹?

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a The value of eff effective magnetic moment for CoF63 is given as 563 B Bohr magnetons However this value does not agree with the value for magnetic moment calculated from the spinonly formula The sp...View the full answer

Inorganic Chemistry

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