By considering the reactions 8E(g) 4E 2 (g) and 8E(g) E 8 (g) for E
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By considering the reactions 8E(g) → 4E2(g) and 8E(g) → E8(g) for E = O and E = S, show that the formation of diatomic molecules is favoured for oxygen, whereas ring formation is favoured for sulfur. [Data: see Table 16.2.]
Table 16.2.
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0-0 146 S-S 266 Se-Se 192 Te-Te 149 0=0 498 S=S 427 O-H 464 S-H 366 Se-H 276 Te-H 238 O-C 359 S-C 272 O-F 190* S-F 326* Se-F 285* Te-F 335* O-CI 205* S-CI 255* Se-Cl 243†
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To determine whether the formation of diatomic molecules or ring formation is favored for oxygen O and sulfur S we need to compare the enthalpy changes H for the two reactions 8Eg 4E2g and 8Eg E8g for E O and E S Lets consider the data from Table 162 for oxygen O and sulfur S For oxygen O Enthalpy change ...View the full answer
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