Classify the symmetry type of the d orbitals in a tetragonal C 4v symmetry complex, such as

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Classify the symmetry type of the d orbitals in a tetragonal C_4v symmetry complex, such as [CoCl(NH₃)₅]²⁺, where the Cl lies on the z-axis.

(a) Which orbitals will be displaced from their position in the octahedral molecular orbital diagram by π interactions with the lone pairs of the Cl⁻ ligand?

(b) Which orbital will move because the Cl⁻ ligand is not as strong a σ base as NH₃?

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Inorganic Chemistry

ISBN: 9780198768128

7th Edition

Authors: Mark Weller, Tina Overton, Jonathan Rourke

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Question Posted: Aug 02, 2023 09:18 AM

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Classify the symmetry type of the d orbitals in a tetragonal C 4v symmetry complex, such as

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In a tetragonal C4v symmetry complex such as CoClNH352 with the Cl ligand lying on the zaxis the d o...View the full answer

Inorganic Chemistry

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