Explain the following observations: (a) The heat of adduct formation of BEt 3 with NMe 3 is
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Explain the following observations:
(a) The heat of adduct formation of BEt3 with NMe3 is −72.3 kJ mol−1, whereas that of B(OMe)3 with the same amine is −31.5 kJ mol−1.
(b) The heat of adduct formation of BMe3 with NMe3 is −75.2 kJ mol−1, whereas with N(SiH3)3 it is about +4 kJ mol−1.
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a The difference in the heat of adduct formation between BEt3 triethylborane and BOMe3 trimethoxyborane with NMe3 trimethylamine can be explained by considering the nature of the substituents on boron ...View the full answer
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Related Book For
Inorganic Chemistry
ISBN: 9780198768128
7th Edition
Authors: Mark Weller, Tina Overton, Jonathan Rourke
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