Explain why a Raman band assigned to the symmetric NC stretching mode in N(CH 3 ) 3

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Explain why a Raman band assigned to the symmetric N–C stretching mode in N(CH3)3 shows a shift to lower frequency when 14N is substituted by 15N but no such shift is observed for the N–Si symmetric stretch in N(SiH3)3.

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Inorganic Chemistry

ISBN: 9780198768128

7th Edition

Authors: Mark Weller, Tina Overton, Jonathan Rourke

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