In 1993, the [Pt(CO) 4 ] 2+ ion was reported for the first time [G. Hwang et
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In 1993, the [Pt(CO)4]2+ ion was reported for the first time [G. Hwang et al. (1993) Inorg. Chem., vol. 32, p. 4667]. One strong absorption at 2235 cm–1 in the IR spectrum was assigned to νCO, and this was absent in the Raman spectrum. In the Raman spectrum, two absorptions (νCO) at 2257 and 2281 cm–1 (absent in the IR spectrum) were observed. Show that these data are consistent with [Pt(CO)4]2+ having D4h symmetry.
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