Ligand 25.35 has been designed for use in Ru-based catalysts for hydrogenation reactions in an EtOH/hexane solvent

Question:

Ligand 25.35 has been designed for use in Ru-based catalysts for hydrogenation reactions in an EtOH/hexane solvent system. These solvents separate into two phases upon the addition of a small amount of water.

(a) For what types of hydrogenations would this catalyst be especially useful? Rationalize your answer.

(b) Ligand 25.35 is related to BINAP (25.14) but has been functionalized. Suggest a reason for this functionalization.

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Related Book For answer-question

Inorganic Chemistry

ISBN: 9781292134147

5th Edition

Authors: Catherine Housecroft

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Question Posted: Jul 26, 2023 04:26 AM

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Ligand 25.35 has been designed for use in Ru-based catalysts for hydrogenation reactions in an EtOH/hexane solvent

Question:

RO HN OR OR RO Ph₂P PPh₂ RO R=CH₂C6H₂-3,4,5-(OC10H21)3 (25.35) OR · ΝΗ O

Step by Step Answer:

a Ligand 2535 has a hydrophilic functional group phosphonic acid moiety POOH2 attached to the aromat...View the full answer

Inorganic Chemistry

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