Reaction of AsCl 3 with Cl 2 at low temperature yields a product, believed to be AsCl

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Reaction of AsCl3 with Cl2 at low temperature yields a product, believed to be AsCl5, which shows Raman bands at 437, 369, 295, 220, 213, and 83 cm−1. Detailed analysis of the 369 and 295 cm−1 bands shows them to arise from totally symmetric modes. Show that the Raman spectrum is consistent with a trigonal-bipyramidal geometry.

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Inorganic Chemistry

ISBN: 9780198768128

7th Edition

Authors: Mark Weller, Tina Overton, Jonathan Rourke

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