The isolation and characterization of a SeSe species with a three-electron sigma bond was described in a
Question:
The isolation and characterization of a Se–Se species with a three-electron sigma bond was described in a paper by Zhang and co-workers (Nat. Commun., 2014, 5, 4127).
(a) Who first proposed the possibility of a three-electron sigma bond?
(b) Sketch the orbital interaction diagram for the formation of the bond.
(c) What was the Se–Se bond length? Discuss how this compares to a single Se–Se bond and explain the difference between them.
(d) Which organic species was used to stabilize the Se–Se bond?
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a Linus Pauling first proposed the possibility of a threeelectron sigma bond in 1931 b The orbital i...View the full answer
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Related Book For 
Inorganic Chemistry
ISBN: 9780198768128
7th Edition
Authors: Mark Weller, Tina Overton, Jonathan Rourke
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