The paper Atypical compounds of gases which have been called noble (Chem. Soc. Rev., 2007, 36, 1632)

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The paper ‘Atypical compounds of gases which have been called “noble”’ (Chem. Soc. Rev., 2007, 36, 1632) provides a thorough account of the range of compounds formed by Group 18 elements. Among the compounds described are XeF5Cl, HXeOOXeH, and ClXeFXeCl+. Sketch the structures of these molecules. Outline the author’s rationale for classing noble-gas atoms as Lewis bases and describe why XeF2 acts as a ligand with metal cations. Only one compound of xenon with mercury was described. Give the formula of this compound, outline its synthesis, and give the Hg–Xe bond energy and bond length.

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Inorganic Chemistry

ISBN: 9780198768128

7th Edition

Authors: Mark Weller, Tina Overton, Jonathan Rourke

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