The Raman spectrum of solid [SeI 3 ][AsF 6 ] contains absorptions at 227, 216, 99 and
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The Raman spectrum of solid [SeI3][AsF6] contains absorptions at 227, 216, 99 and 80 cm–1 assigned to the vibrational modes of the [SeI3]+ ion. Explain the origins of the four absorptions. Draw diagrams to represent the modes of vibration, and assign a symmetry label to each mode.
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