The reaction of trans-[Pt(PEt 3 ) 2 PhCl] with the strong nucleophile thiourea (tu) in MeOH follows

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The reaction of trans-[Pt(PEt3)2PhCl] with the strong nucleophile thiourea (tu) in MeOH follows a 2-term rate law with

image

A plot of kobs against [tu] is linear with the line passing close to the origin. Rationalize these observations.image


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Inorganic Chemistry

ISBN: 9781292134147

5th Edition

Authors: Catherine Housecroft

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