When RhBr 3 in the presence of MePh 2 As is treated with H 3 PO 2

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When RhBr3 in the presence of MePh2As is treated with H3PO2, a monomeric compound X is formed. X contains 2Br and 3MePh2As per Rh, and is a non-electrolyte. Its IR spectrum has a band at 2073 cm−1, and the corresponding band if the complex is made using D3PO2 in a deuterated solvent is 1483 cm−1. Spectrophotometric titration of X with Br2 shows that one molecule of X reacts with one molecule of Br2; treating the product with excess mineral acid regenerates RhBr3. What can you conclude about the products?

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Inorganic Chemistry

ISBN: 9781292134147

5th Edition

Authors: Catherine Housecroft

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