In our discussion of departure functions we derived Eqn. 8.14 for the internal energy departure for any

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In our discussion of departure functions we derived Eqn. 8.14 for the internal energy departure for any equation of state.

(a) Derive the analogous expression for (CV - CVig)/R.

(b) Derive an expression for (CV - CVig)/R in terms of a, b, ρ, and T for the equation of state:Z=1+ bp 1+bp -p[exp(a/T)-1]

P 1 (OP URY-SRTG) 18 = -r (7) de  OT 0 U-Us = PROT 8.14

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