With V 2 = V 2 , Eq. (15.66) for the osmotic pressure may be represented as
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With V̅2 = V2, Eq. (15.66) for the osmotic pressure may be represented as a power series in x1:
Reminiscent of Eqs. (3.33) and (3.34), this series is called an osmotic virial expansion. Show that the second osmotic virial coefficient B is:
What is B for an ideal solution? What is B if GE = A x1 x2 ?
Eq. (15.66)
Eqs. (3.33) and (3.34)
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Related Book For
Introduction To Chemical Engineering Thermodynamics
ISBN: 9781259696527
8th Edition
Authors: J.M. Smith, Hendrick Van Ness, Michael Abbott, Mark Swihart
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