Derive an expression for the equilibrium constant (K(T)) for the reaction (mathrm{H}_{2}+mathrm{D}_{2} leftrightarrow 2 mathrm{HD}) at temperatures
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Derive an expression for the equilibrium constant \(K(T)\) for the reaction \(\mathrm{H}_{2}+\mathrm{D}_{2} \leftrightarrow 2 \mathrm{HD}\) at temperatures high enough to allow classical approximation for the rotational motion of the molecules. Show that \(K(\infty)=4\).
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We extend the treatment of Problem 314 to the reaction A BC D leftrightarrow A DC B and obtain in eq...View the full answer
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