According to Equation 9.30, the vibrationrotation constant for a harmonic oscillator is not zero and is in
Question:
According to Equation 9.30, the vibration–rotation constant for a harmonic oscillator is not zero and is in fact negative. Consider the rotational constant for the v = 0 state of a harmonic oscillator, which is proportional to the expectation value {1/R}V = 0. Show that this expectation value is greater than 1/R2e, thus B0 for a harmonic oscillator is greater than Be, resulting in a negative vibration–rotation coupling constant.
Equation 9.30
Transcribed Image Text:
de -2B²2B₂RV(3) 2B, R/V + 3} +3 hv² Ve
Fantastic news! We've Found the answer you've been seeking!
Step by Step Answer:
Answer rating: 0% (2 reviews)
The equation provided represents the vibrationrotation interaction constant a for a diatomic molecul...View the full answer
Answered By
Aysha Ali
my name is ayesha ali. i have done my matriculation in science topics with a+ . then i got admission in the field of computer science and technology in punjab college, lahore. i have passed my final examination of college with a+ also. after that, i got admission in the biggest university of pakistan which is university of the punjab. i am studying business and information technology in my university. i always stand first in my class. i am very brilliant client. my experts always appreciate my work. my projects are very popular in my university because i always complete my work with extreme devotion. i have a great knowledge about all major science topics. science topics always remain my favorite topics. i am also a home expert. i teach many clients at my home ranging from pre-school level to university level. my clients always show excellent result. i am expert in writing essays, reports, speeches, researches and all type of projects. i also have a vast knowledge about business, marketing, cost accounting and finance. i am also expert in making presentations on powerpoint and microsoft word. if you need any sort of help in any topic, please dont hesitate to consult with me. i will provide you the best work at a very reasonable price. i am quality oriented and i have 5 year experience in the following field.
matriculation in science topics; inter in computer science; bachelors in business and information technology
_embed src=http://www.clocklink.com/clocks/0018-orange.swf?timezone=usa_albany& width=200 height=200 wmode=transparent type=application/x-shockwave-flash_
4.40+
11+ Reviews
14+ Question Solved
Related Book For
Question Posted:
Students also viewed these Sciences questions
-
According to quantum mechanics, the energy of a harmonic oscillator is quantized. That is, it can take on any one of a certain set of values, given by where h is Plancks constant, equal to 6.62608...
-
For a harmonic oscillator of effective mass 2.88 x 10-25kg, the difference in adjacent energy levels is 3.17 z calculate the force constant of the oscillator.
-
The ground-state energy of a harmonic oscillator is 5.60eV. If the oscillator undergoes a transition from its n = 3 to n = 2 level by emitting a photon, what is the wavelength of the photon?
-
Dr. Bold has a personal automobile policy with liability limits as follows: $100,000/$300,000 BI and $50,000 PD. Dr. Bold is held liable in an accident in which he must pay for bodily injuries as...
-
Zurg Corp. uses the direct method to prepare its statement of cash flows. Zurgs trial balances at December 31, 2014 and 2013 are as follows. Additional information: 1. Zurg purchased a major piece of...
-
Maltonese Inc. has 5 million shares outstanding selling at $60 each, and its price-to earningsratio (P/E) is 10. Targeton Corp. has 1.5 million shares outstanding with a market price of $30 each, and...
-
A solid conducting sphere of radius \(R\) is embedded in an electrically neutral nonconducting spherical shell that has inner radius \(R\), has outer radius \(2 R\), and is made of a material having...
-
In recent years, Darnell Company purchased three machines. Because of heavy turnover in the accounting department, a different accountant was in charge of selecting the depreciation method for each...
-
11. If a,b,x,ye R,@ #1, is a cube root of unity and (a+b)=x+yo, then (b+aw)' equals: (a) y+x@ 6 (c) -y-xw 12. The value of S = sin- -icos- (c) y+yw (d) -x-ya 2k is: 7 (c)-i (d) i , then value of...
-
Use the data in Table 9.2 to assign the Q branch lines in Figure 9.6. Account for the relative intensities. Figure 9.6 Table 9.2 Spectroscopic constants for diatomics in the ground electronic state...
-
Use the harmonic oscillator raising and lowering operators to derive the selection rules for vibrational transitions that result from electrical anharmonicity in the form (/dq)oq.
-
For most companies in todays business world, profits (also referred to as the bottom line) are the standard measurement of success. But the past decade has seen a dramatic rise in a different model:...
-
respond to Cases # 3 & 8 on Answer each question posed in the cases. 3. One of the most widely known criminal trials in recent memory involved that of comedian Bill Cosby, who was accused, in that...
-
Consider and discuss the potential areas that a new ethical purchasing policy needs to address. These include: a) the rationale for why Fat-E should have a corporate ethical policy, b) who the policy...
-
The article "FASB Approves Expanded Tax Disclosure Requirements for Companies Despite Opposition" by Mark Maurer (2023) delves into the recent approval by the Financial Accounting Standards Board...
-
LJ, married, has two dependent minor brothers. He is a partner of a general professional partnership. He is also engaged in trading business of his own. The following data were provided by LJ in...
-
Managed care: Group of answer choices provides retrospective payment determined by the number of services provided to a patient. recognizes and maintains separate responsibilities for the payer and...
-
The last 106 baseball seasons (as of this writing) ended with 62 World Series wins by American League teams, compared to 44 wins by National League teams. Use the sign test with a 0.05 significance...
-
In a nonmagnetic medium, E = 50 cos (10 9 t 8x) a y + 40 sin (10 9 t 8x) a z V/m find the dielectric constant r and the corresponding H.
-
How many constitutional isomers are obtained when each of the following compounds undergoes monochlorination? (a) (b) (c) (d) (e) (f) (g) (h) (i) (j)
-
Propylene is produced by cracking petroleum and is a very useful precursor in the production of many useful polymers. Propylene has one constitutional isomer. Draw that isomer, and identify its...
-
Identify the reagents you would use to achieve each of the following transformations: (a) (b) (c) (d) (e) OTs `CN
-
Barak purchased a parcel of land for $ 6 5 , 0 0 0 . He also paid commissions of $ 1 , 0 0 0 , title fee of $ 1 2 5 , survey fee of $ 1 5 0 , legal fees of $ 1 , 5 0 0 , and two months later...
-
Critically evaluate why external Auditors needs to be regulated 2 . Explain why there should be separation of duties between Chief Executive Officers and the chairman of the Board of Directors? 3...
-
Jasmine sold a rental property for $ 6 7 5 , 0 0 0 in the current year. She had initially purchased the property for $ 5 0 0 , 0 0 0 . Jasmine replaced the roof two years ago for $ 3 5 , 0 0 0 and...
Study smarter with the SolutionInn App