Consider the reaction of a methyl radical (CH3) with the p bond of an alkene: The relative

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Consider the reaction of a methyl radical (·CH3) with the p bond of an alkene: R R T Hoa C=C + CH3 R R R R R R C-C-CH3

The relative rates of the reaction shown in Fig. P5.50 were determined for various alkenes.

(a) Draw the free-radical product of the reaction in each case and explain.

(b) Explain the order of the relative rates. alkene: relative rate: Figure P5.50 HC=CH 1.0 (CH3)2C=CH (CH3)2C CHCH3 1.4 0.077

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Organic Chemistry

ISBN: 9781936221349

6th Edition

Authors: Marc Loudon, Jim Parise

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Question Posted: Nov 26, 2023 12:07 AM

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Consider the reaction of a methyl radical (CH3) with the p bond of an alkene: The relative

Question:

R R T Hoa C=C + CH3 R R R R R R •C-C-CH3

Step by Step Answer:

a The methyl radical reacts at the carbon of the double bond with fewer substituents because this mode of reaction gives the more substituted radical ...View the full answer

Organic Chemistry

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