Draw a curved-arrow mechanism for the Amadori rearrangement in Eq. 27.50. Let H 3 O + and
Question:
Draw a curved-arrow mechanism for the Amadori rearrangement in Eq. 27.50. Let H3O+ and H2O be the acid–base pair, present as necessary.
Transcribed Image Text:
HO HO HOCH₂ ОН Amadori rearrangement -CH=N-Hb ОН glucose-Hb imine (Schiff base) HO НО Н OH HO НО HỌCH, -CH₂OH Н 11 ОН -CH,-NH-НЬ internal rotation -CH2-ЙН_НЬ НО ОН ОН -ОН CH,-NH-НЬ Amadori product (27.50)
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