Treatment of (S)-(+)-5-methyl-2-cyclohexenone with lithium dimethylcuprate gives, after protonolysis, a good yield of a mixture containing mostly

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Treatment of (S)-(+)-5-methyl-2-cyclohexenone with lithium dimethylcuprate gives, after protonolysis, a good yield of a mixture containing mostly a dextrorotatory ketone A and a trace of an optically inactive isomer B. Treatment of A with zinc amalgam and HCl affords an optically active, dextrorotatory hydrocarbon C. Identify A, B, and C, and give the absolute stereochemical configurations of A and C.

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Organic Chemistry

ISBN: 9781936221349

6th Edition

Authors: Marc Loudon, Jim Parise

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