a. Realizing that the most probable outcome from a series of N coin tosses is N/2 heads

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a. Realizing that the most probable outcome from a series of N coin tosses is N/2 heads and N/2 tails, what is the expression for Wmaxcorresponding to this outcome?

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b. Given your answer for part (a), derive the following relationship between the weight for an outcome other than the most probable and Wmax:

= -Hlog N/2 log н – T log т N/2

c. We can define the deviation of a given outcome from the most probable outcome using a €œdeviation index,€ α = H €“ T / N. Show that the number of heads or tails can be expressed as H = N / 2 (1 + α) and T = N / 2 (1 €“ α).

d. Finally, demonstrate that

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Physical Chemistry

ISBN: 978-0321812001

3rd edition

Authors: Thomas Engel, Philip Reid

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