At 273 K measurements on argon gave B = 21.7 cm 3 mol 1 and C =

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At 273 K measurements on argon gave B = −21.7 cm3 mol−1 and C = 1200 cm6 mol−2 , where B and C are the second and third virial coefficients in the expansion of Z in powers of 1/Vm. Assuming that the perfect gas law holds sufficiently well for the estimation of the second and third terms of the expansion, calculate the compression factor of argon at 100 atm and 273 K. From your result, estimate the molar volume of argon under these conditions.

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Physical Chemistry

ISBN: 9780716787594

8th Edition

Authors: Peter Atkins, Julio De Paula

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