For a closed-shell atom, an anti-symmetric wave function can be represented by a single Slater determinant. For
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For a closed-shell atom, an anti-symmetric wave function can be represented by a single Slater determinant. For an open-shell atom, more than one determinant is needed. Show that the wave function for the MS = 0 triplet state of He 1s12s1 is a linear combination of two of the Slater determinants of Example Problem 21.2. Which of the two are needed and what is the linear combination?
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By comparing the first term in the expanded equation for triplet with the eight ter...View the full answer
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