For a particle in a two-dimensional box, the total energy eigenfunctions are a. Obtain an expression for

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For a particle in a two-dimensional box, the total energy eigenfunctions are

            Wn,n, (x, y) = Nsin- n,ty плх sin-

a. Obtain an expression for Enx, ny in terms of nx, ny, a, and b by substituting this wave function into the two dimensional analog of Equation (15.19).

b. Contour plots of several eigenfunctions are shown here. The x and y directions of the box lie along the horizontal and vertical directions, respectively. The amplitude has been displayed as a gradation in colors. Regions of positive and negative amplitude are indicated. Identify the values of the quantum numbers nx and ny for plots a€“f.

0.5 0.5 0.4 0.4 0.3 0.3 0.2 0.2 0.1 0.1 0.1 0.2 0.3 0.4 0.5 0.1 0.2 0.3 0.4 0.5 (a) (b) 0.5 0.5 0.4 0.4 0.3 0.3 0.2 0.2

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Physical Chemistry

ISBN: 978-0321812001

3rd edition

Authors: Thomas Engel, Philip Reid

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