For a van der Waals gas, z = V m /(V m b) a/RTV m

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For a van der Waals gas, z = V_m/(V_m − b) − a/RTV_m. Expand the first term of this expression in a Taylor series in the limit V_m >> b to obtain z ≈ 1 + (b − a/RT)(1/V_m).

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Physical Chemistry

ISBN: 978-0321812001

3rd edition

Authors: Thomas Engel, Philip Reid

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Question Posted: Apr 30, 2018 12:41 AM

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For a van der Waals gas, z = V m /(V m b) a/RTV m

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Physical Chemistry

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