From the results of Exercise 17.5a, calculate the rotational contribution to the molar entropy of gaseous water

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From the results of Exercise 17.5a, calculate the rotational contribution to the molar entropy of gaseous water at 25°C.


Data in  Exercise 17.5a,

Calculate the rotational partition function of H2O at 298 K from its rotational constants 27.878 cm−1, 14.509 cm−1, and 9.287 cm−1. Above what temperature is the high-temperature approximation valid to within 10 per cent of the true value?

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Physical Chemistry

ISBN: 9780716787594

8th Edition

Authors: Peter Atkins, Julio De Paula

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