Given the limitations of the Langmuir model, many other empirical adsorption isotherms have been proposed to better

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Given the limitations of the Langmuir model, many other empirical adsorption isotherms have been proposed to better reproduce observed adsorption behavior. One of these empirical isotherms is the Temkin isotherm: V adsorbed = r ln (sP), where V is the volume of gas adsorbed, P is pressure, and r and s are empirical constants.

a. Given the Temkin isotherm provided, what type of plot is expected to give a straight line?

b. Use your answer from part (a) to determine r and s for the data presented in Problem P36.24.

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Physical Chemistry

ISBN: 978-0321812001

3rd edition

Authors: Thomas Engel, Philip Reid

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