In deriving the vibrational partition function, a mathematical expression for the series expression for the partition function

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In deriving the vibrational partition function, a mathematical expression for the series expression for the partition function was employed. However, what if one performed integration instead of summation to evaluate the partition function? Evaluate the following expression for the vibrational partition function:

- βhon n Σe βho Σ n=0 Ξ βhcn

Under what conditions would you expect the resulting expression for qV to be applicable?

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Physical Chemistry

ISBN: 978-0321812001

3rd edition

Authors: Thomas Engel, Philip Reid

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