In the troposphere carbon monoxide and nitrogen dioxide undergo the following reaction: NO 2 (g) + CO(g)

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In the troposphere carbon monoxide and nitrogen dioxide undergo the following reaction:

NO2(g) + CO(g) → NO(g) + CO2(g)

Experimentally, the rate law for the reaction is second order in NO2(g), and NO3(g) has been identified as an intermediate in this reaction. Construct a reaction mechanism that is consistent with these experimental observations.

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Physical Chemistry

ISBN: 978-0321812001

3rd edition

Authors: Thomas Engel, Philip Reid

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