Nitrogen dioxide reacts bimolecularly in the gas phase to give 2 NO + O 2 . The
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Nitrogen dioxide reacts bimolecularly in the gas phase to give 2 NO + O2. The temperature dependence of the second-order rate constant for the rate law d[P]/dt = k[NO2]2 is given below. What are the P factor and the reactive cross-section for the reaction?
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T/K k/(cm³ mol-¹ s-¹) Take o=0.60 nm². 600 4.6 x 10² 700 9.7 x 10³ 800 1.3 x 105 1000 3.1 x 106
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