Set up the secular determinants for cyclobutadiene, benzene, and cyclooctatetraene and diagonalize them by using mathematical software.
Question:
Set up the secular determinants for cyclobutadiene, benzene, and cyclooctatetraene and diagonalize them by using mathematical software. Use your results to show that the π molecular orbitals of monocyclic polyenes with an even number of carbon atoms follow a pattern in which:
• The π molecular orbitals of lowest and highest energy are non-degenerate.
• The remaining π molecular orbitals exist as degenerate pairs.
Fantastic news! We've Found the answer you've been seeking!
Step by Step Answer:
Answer rating: 66% (9 reviews)
Proof The molecular orbitals of cyclobutadiene C 6 H 6 benzene C 6 H 6 and cyclooctatetraene C 12 H ...View the full answer
Answered By
James Warinda
Hi! I’m James Otieno and I'm an experienced professional online tutor with countless hours of success in tutoring many subjects in different disciplines. Specifically, I have handled general management and general business as a tutor in Chegg, Help in Homework and Trans tutor accounts.
I believe that my experience has made me the perfect tutor for students of all ages, so I'm confident I can help you too with finding the solution to your problems. In addition, my approach is compatible with most educational methods and philosophies which means it will be easy for you to find a way in which we can work on things together. In addition, my long experience in the educational field has allowed me to develop a unique approach that is both productive and enjoyable.
I have tutored in course hero for quite some time and was among the top tutors awarded having high helpful rates and reviews. In addition, I have also been lucky enough to be nominated a finalist for the 2nd annual course hero award and the best tutor of the month in may 2022.
I will make sure that any student of yours will have an amazing time at learning with me, because I really care about helping people achieve their goals so if you don't have any worries or concerns whatsoever you should place your trust on me and let me help you get every single thing that you're looking for and more.
In my experience, I have observed that students tend to reach their potential in academics very easily when they are tutored by someone who is extremely dedicated to their academic career not just as a businessman but as a human being in general.
I have successfully tutored many students from different grades and from all sorts of backgrounds, so I'm confident I can help anyone find the solution to their problems and achieve
0.00
0 Reviews
10+ Question Solved
Related Book For
Physical Chemistry Thermodynamics And Kinetics
ISBN: 9781464124518
10th Edition
Authors: Peter Atkins, Julio De Paula
Question Posted:
Students also viewed these Sciences questions
-
A fatty acid with an even number of carbon atoms is metabolized to acetyl-CoA, which can enter the citric acid cycle. A fatty acid with an odd number of carbon atoms is metabolized to acetyl-CoA and...
-
Set up the secular determinants for the homologous series consisting of ethene, butadiene, hexatriene, and octatetraene and diagonalize them by using mathematical software. Use your results to show...
-
Set up and solve the secular determinants for (a) hexatriene, (b) the cyclopentadienyl radical in the Hckel p-electron scheme; find the energy levels and molecular orbitals, and estimate the...
-
Calculate the density of N2 at STP, (a) using the ideal-gas law and (b) using the molar volume and molar mass of N2. How do the densities compare?
-
Customer checks and remittance advices are received in the mailroom each morning along with the general mail. Mail volume is typically high requiring a mailroom staff of 40 clerks and one supervisor....
-
A manufacturer provides specialized microchips. During the next 3 months its sales, costs, and available time are There are no chips in stock at the beginning of the first month. It takes 1.5 hrs of...
-
A computer system administrator notices that computers running a particular operating system seem to freeze up more often as the installation of the operating system ages. She measures the time (in...
-
Calculating Annuity Values If you deposit $3,000 at the end of each of the next 20 years into an account paying 10.5 percent interest, how much money will you have in the account in 20 years how much...
-
PolyU Ltd. is considering a project. The equipment required will cost $150,000 and will be depreciated to zero over its 5-year life. The market value of the equipment will be $30,000 five years...
-
Yolo Windows, a manufacturer of windows for commercial buildings, reports the following account information for last year (all costs are in thousands of dollars): Information on January 1...
-
Use mathematical software to estimate the -electron binding energy of (i) azulene (3), (ii) acenaphthalene (4) within the Hckel approximation. 3 Azulene 4 Acenaphthalene
-
Explain why the use of Gaussian-type orbitals is generally preferred over the use of hydrogenic (exponential) orbitals in basis sets.
-
What are the components of the following systems? Draw and explain the configuration of each. (a) Barbershop (b) Car wash (c) Laundromat (d) Small grocery store
-
less than 10% of your total Calories per day should come fromadded sugar. To calculate number of calories from added sugars,take the grams of added sugars you consumed per day (not over 2days) and...
-
Design a strategy to eliminate oppressive structural barriers evident in their client case writing 1. Identifying human rights or social, economic, or environmental justice violation, how this...
-
SCHEDULE 3 (Form 1040) Department of the Treasury Internal Revenue Service Additional Credits and Payments Attach to Form 1040, 1040-SR, or 1040-NR. Go to www.irs.gov/Form 1040 for instructions and...
-
Nassau Products is preparing a cash budget for April. The following information on accounts receivable collections is available from past collection experience: Percent of current month's sales...
-
The sampling results for the chemical hazards you tested for Acme Automotive Parts (AAP) are listed in the following table. The volumes that are listed are what you provided to the laboratory. Hazard...
-
Determine the dimension of and a basis for the solution space of the system. x1 - 3x2 + x3 = 0 2x1 - 6x2 + 2x3 = 0 3x1 - 9x2 + 3x3 = 0
-
The figure shows a bolted lap joint that uses SAE grade 8 bolts. The members are made of cold-drawn AISI 1040 steel. Find the safe tensile shear load F that can be applied to this connection if the...
-
Why does an increase in the ionic strength in the range where the DebyeHckel law is valid lead to an increase in the solubility of a weakly soluble salt?
-
What is the correct order of the following inert electrolytes in their ability to increase the degree of dissociation of acetic acid? a. 0.001m NaCl b. 0.001m KBr c. 0.10m CuCl 2
-
How does salting in affect solubility?
-
A 3.0 resistor is connected across the terminals of a 100 V battery. If 0.50 A of current flows, what is the internal resistance of the battery?
-
The rate of blood flow through the aorta is Q = 100 cm/s. A capillary has an average cross sectional area of Acap = 3 x10 -11 m and supports a blood speed of cap = 1 mm/s. From this information, what...
-
A particle is trapped in a potential well described by U(x)=16-b where U is in joules, x is in meters, and b= 4.0 J. Find the force on the particle when it's at a) x=2.2m and b) x=-1.7m.
Study smarter with the SolutionInn App